ill agree to differ on it if you will mate, no offence but thats what i used to think but a bit of research (anal stylie) and with some help from this forum this is my new approach to suction / adhesion..
normally adhesion is created by suction, the wall pulls the stuff in so it sticks... think overskim, board etc...
pva will kill excess suction so it doesnt 'burn' like skimming over old bonding without killing at least 'some' suction...
gloss paint... pva it and hit it with multi or even board, it gonna give you nightmares, slide all over the wall, etc.. try a  sharpish round corner on gloss paint, pva'd or not...
silk paint... long as its well stuck to the wall, it'll still give you a little bit of suction, no pva, works ok...
pva it and the pva will run down the wall in streaks, hit it with plaster it'll give you problems...
gypbond it however, and hit it with board finish and the grit will stop it sliding, hold it to the wall and youll have ages to trowel it up but without the ripples you get without a key cos its moving as you trowel it...
silk paint that aint stuck.. your f'cked...
gloss paint without gypbond... your f'cked...
concrete, pva, dry, long as it doesnt slide you can trowel it up ok but has it actually stuck? pva lives up when it gets wet, thats why theres pva and 'waterproof' pva...
moisture resistant boards are recomended to use gypbond cos theres no suction, they dont recomend pva.. just read a bag of boardy...
i got my tips off gary b, put it to the test, and i find the guys bang on....
boardy for low suction, gypbond for no / very little suction and multi + pva for medium / high suction...
now thats just my mindset....
example though... my mate thought the same, pva over silk, let it go tacky, it'll give a key... f'ckin loads of problems this week for that exact reason, so i introduced a tub of wba i had on the van and a few bags of boardy...
first thing he says? ' no chance' didnt trust it or me, made a real small set, scared of it...
end of set whats he say? 'can you buy it in bigger tubs?'
i.ve always thought pva gives a 'key'...
now i think / 'know' its suction control only...
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