I'm sorry, but some of your assertions are wrong.
Firstly there is no need to 'buffer moisture levels in the internal air'. It is as we all agree essential to allow a solid wall to breathe, which can be achieved either into the room itself, or into a cavity. That preserves the moisture flow through the wall structure, but prevents significant heat loss which is quite basic physics when you think about it. If that wasn't the case then cavity wall construction wouldn't work. It allows the outer skin to breathe and the cavity to dry to the outside.
Moisture levels inside the inner box formed by the insulation are balanced across extraction in the areas of highest moisture concentration, opening and closing doors, people exhaling, 'dry' heating systems, weep vents etc. Interstitial condensation isn't an issue as the cavity is vented which allows exchange of air yet still maintains drying to the outside. However, the drying effect is at a more constant rate as there is a much reduced temperature range of peaks and troughs because the inner face of the wall isn't exposed to the heating and cooling cycles caused by the houses heating systems.
So whilst I agree that an impermeable layer in contact with, or forming part of, the outer wall would be a bad approach, forming a vented internal cavity would most definitely not. As mentioned above, if it were then every building of cavity wall construction wouldn't work.